Lily Allen - Having already wowed Glastonbury in a purple wig and catsuit, Lily is set to make another charismatic appearance at V. Expect to hear hits from her latest album 'It's Not Me, It's You' as well as classics like 'LDN' and 'Smile' alongside her inimitable cheeky wit and her cover of Britney's 'Womaniser'. Fingers crossed she will make it through the show without bursting into tears as she did at a recent festival show in Finland.
5 of 20

Coachella Festival 2012: The Must-See Acts
Bestival Festival 2011: Pop Stars, Rock Stars And Divas Fancy Dress Photos
Bestival Festival 2011: The Best Bits In Photos
Bestival Festival 2011: Photos From Day Three
The 15 Best B-Sides Of All Time
Oasis, Blur, Rage Against The Machine: The Greatest Rock Acts Of The 90s
Liam Gallagher: I'd Prefer To Still Be In Oasis Than Beady Eye
Oasis, Stone Roses, The Smiths: We're Mad About Manchester
Use A Condom This Valentines Day: Musicians And Their 'Love Child'
What Came First, The Music Or The Misery? The Anti-Valentine's Day Playlist
From Whitney Houston to Michael Jackson: Grammy Awards Most Memorable Moments Ever 